Optimization and modeling of extraction equilibria of the type 2 ternary systems containing (water plus isovaleric acid plus solvent)

Senol A.

JOURNAL OF CHEMICAL THERMODYNAMICS, cilt.91, ss.211-224, 2015 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 91
  • Basım Tarihi: 2015
  • Doi Numarası: 10.1016/j.jct.2015.07.035
  • Dergi Adı: JOURNAL OF CHEMICAL THERMODYNAMICS
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.211-224
  • İstanbul Üniversitesi Adresli: Evet

Özet

The extraction equilibria of the type 2 ternary systems containing (water + isovaleric acid + solvent) have been investigated at T = (298.2 +/- 0.1) K and P = (101.3 +/- 0.7) kPa. Aromatic solvents xylene, chlorobenzene and benzyl ether give the largest distribution ratios and separation factors, as compared to 1-phenyl ethanol, cyclohexanol and 1-decanol. The distribution data have been subjected to formulation of an optimization structure for an effective acid separation. The optimization approach uses a derivative variation method to efficiently identify the optimization range through analyzing the first order derivatives of the optimized quantity and the non-linear deviation profile of the derivative value. Some aspects of selection of an appropriate criterion for designing optimum extraction are discussed.